Spring 1996

CH 313:  PHYSICAL ORGANIC CHEMISTRY

R.D. Libby 
213 Collier
Ext. 1436
Class Hours 
MWF 11:30 AM - 12:20 PM
Th 10:20-11:10 AM
200 CHS 
Office Hours
Mon.   2:00 ->   3:00 PM
Tues. 10:30 -> 11:30 AM
Wed. 12:30 ->   1:30 PM
Fri.    12:30 ->   1:30 PM
Or any time, just call X1436

Text: "Mechanism and Theory in Organic Chemistry", 3rd Ed., by Thomas H. Lowry and Kathleen Schueller Richardson(L&R).

Syllabus:

 

Topic

Reading

I. Bonding and Molecular Orbital Theory L&R: Chapt. 1 & Appendix 1
II. Theory and Applications of Pericyclic Reactions L&R: Chapts. 10&11
III. Radical Reactions L&R: Chapt: 9 & Sec. 2.2
IV. Photochemistry L&R: Chapt: 12
V. Acidity Functions & Acid-Base Chemistry L&R: Chapt: 3 & Secs. 2.3->2.7
VI. Carbanions and Carbenes L&R: Chapt: 6 & Sec. 2.1
VII. Aliphatic Nucleophilic Substitution L&R: Chapt: 4 & Secs. 2.8&2.9
VIII. Cationic Rearrangements L&R: Chapt: 5
IX. Addition and Elimination Reactions L&R: Chapt: 7
X. Reactions of Carbonyl Compounds L&R: Chapt: 8

Grading:

This semester there will be four problem sets and a final exam. The problem sets will be distributed and collected as indicated below and will account for 75 % of the course grade. The final exam will be written during the examination period and will account for 25 % of the course grade.

Schedule for Problem Sets:

Problem Set Distribution Date Collection Date
#1 Mon., Feb. 5 Mon., Feb. 12
#2 Mon., Feb. 26 Mon., Mar. 4
#3 Mon., Mar. 25 Mon., Apr. 1
#4 Mon., Apr.15 Mon., Apr.22